Benzo[h]quinolin-10-yl-NIridium(III) Complexes
نویسندگان
چکیده
منابع مشابه
2-(5-Bromothiophen-2-yl)-5-[5-(10-ethylphenothiazin-3-yl)thiophen-2-yl]-1,3,4-oxadiazole
The mol-ecule of the title compound, C(24)H(16)BrN(3)OS(3), contains three approximately planar fragments, viz. an oxadiazole ring plus two adjacent thio-phene groups, and two phenothia-zine benzene rings, with largest deviations from the least-squares planes of 0.051 (3), 0.019 (4) and 0.014 (3) Å, respectively. The phenothia-zine unit adopts a butterfly conformation, with a dihedral angle of ...
متن کامل1-(10H-phenothiazin-10-yl)ethanone
In the title compound, C14H11NOS, the phenothia-zine unit has a butterfly conformation and the central six-membered ring has a boat form. The fold angle between the benzene rings is 46.39 (7)°, which is larger than found in similar compounds, probably as a result of steric repulsion between the phenothia-zine fragment and the acetyl group.
متن کامل1-(10-Bromoanthracen-9-yl)-1H-imidazole
In the title mol-ecule, C17H11BrN2, the planes of the anthracene ring system [maximum deviation from the mean plane = 0.036 (3) Å] and the imidazole ring form a dihedral angle of 85.14 (14)°. In the crystal, weak C-H⋯N and C-H⋯Br hydrogen bonds link the mol-ecules into double chains propagating along [01-1]. In addition, π-π stacking inter-actions between pairs of benzene rings are observed, wi...
متن کاملPhosphine-Substituted Diborane(4)yl Complexes of Tungsten
The reaction of the 1,2-dihalodiborane(4) B2(NMe2)2Cl2 with the lithium tungsten salts Li[(η5C5H5)(R3P)(OC)2W] [R = Me (3a), Ph (3b)] yields via alkali salt elimination the phosphinesubstituted diborane(4)yl tungsten complexes [(η-C5H5)(R3P)(OC)2W-{B(NMe2)-B(NMe2)Cl}] [R = Me (4a), Ph (4b)]. Both compounds have been fully characterized in solution by NMR and IR spectroscopy and 4a additionally ...
متن کاملTuning Coordination in s-Block Carbazol-9-yl Complexes
1,3,6,8-Tetra-tert-butylcarbazol-9-yl and 1,8-diaryl-3,6-di(tert-butyl)carbazol-9-yl ligands have been utilized in the synthesis of potassium and magnesium complexes. The potassium complexes (1,3,6,8-tBu4carb)K(THF)4 (1; carb = C12H4N), [(1,8-Xyl2-3,6-tBu2carb)K(THF)]2 (2; Xyl = 3,5-Me2C6H3) and (1,8-Mes2-3,6-tBu2carb)K(THF)2 (3; Mes = 2,4,6-Me3C6H2) were reacted with MgI2 to give the Hauser ba...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1974
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.47.767